Friday, January 24, 2020

The 1918-1919 Influenza Epidemic Essay -- The Great Influenza Pandemic

â€Å"I made money rapidly,† Charles Sligh explained, â€Å"The demands for flowers frequently were so great that all the florists in this community exhausted their supply daily, and the prices of everything were very high then.†1 Along with florists, funeral directors, and orderlies were also making a killing during World War One. â€Å"The undertaker which was half a block away from me had pine boxes on the sidewalk, pilled high. Me and two of my friends would go down there and play on those boxes; it was like playing on the pyramids.†2 Although business was booming for these professions, it was not because of the war. It was the result of an unexpected killer that swept across the world claiming victims at an unprecedented rate. The 1918-1919 influenza pandemic stretched its lethal tentacles all over the globe, even to the most remote areas of the planet, killing fifty million people or possibly even more. Influenza killed more people in a year than the Black Death of the Middle Ages killed in a century, and it killed more people in twenty-four weeks than AIDS has killed in twenty-four years.3 Influenza normally kills the elderly and infants, but this deadly and abnormal strand claimed young people, those in their twenties or thirties as its target victims. Such was the case for Jules Bergeret. Jules was a â€Å"big, strapping man† who owned a tavern during the epidemic, and on December 11 he celebrated his 32 birthday. Within two weeks Jules, his mother, his sister, and his 25 year old wife all fell victim to the flu, and on December 22 he was dead.4 The virus left victims bleeding out of their nose ears and mouth; some coughing so hard that autopsies would later show that abdominal muscles an d rib cartilage had been torn. Victims ... ...: A Survey, (1927) John. M. Barry, The Great Influenza, The Story of the Deadliest Pandemic in History (New York: Penguin, 2004), 179 â€Å"Gauze Masks for men on port keep Flu away,† Stars and Stripes, November, 1, 1918. Nancy K. Bristow, American Pandemic, The Lost Worlds of the 1918 Influenza Epidemic (New York: Oxford University Press, 2012), 193 John. M. Barry, The Great Influenza, The Story of the Deadliest Pandemic in History (New York: Penguin, 2004), 171 Nancy K. Bristow, American Pandemic, The Lost Worlds of the 1918 Influenza Epidemic (New York: Oxford University Press, 2012), 156 Anne A. Colon, â€Å"Experiences during the Epidemic,† The American Journal of Nursing (1919): 607 â€Å"Spanish Influenza†, Journal of the American Medical Association 71(8):660 Katherine Anne Porter, Pale Horse, Pale Rider (United States: The Modern Library, 1936), 255

Thursday, January 16, 2020

Borohydride Reduction

John Heger CMY 211 Lab Section 13 11-30-2011 Borohydride Reduction of Vanillin to Vanillyl Alcohol Introduction: The purpose of this lab was to reduce vanillin to vanillyl alcohol. This lab report recaps the procedure and results of the lab. The chemical process studied in this lab was reduction, the process of reducing the number of bonds to oxygen and increasing the number of bonds to hydrogen. Other chemical processes included in the lab were recrystallization, melting point, and extraction.Procedure: Preparation of Vanillyl Alcohol 2. 5 mmol of vanillin were dissolved in 2. 5 mL of 1 M NaOH solution in a 25 mL Erlenmeyer flask. The flask was swirled to produce a homogeneous yellow solution. The flask was swirled in an ice-water bath for 1-2 minutes and the solution was cooled to approximately 10Â °C. 1. 95 mmol of NaBH4 was added while the solution was constantly swirled. It was added in three to four portions over a period of 3 minutes. The solution was allowed to stand undistu rbed for 30 minutes at room temperature.After the time period, the flask was cooled in an ice-water bath and 3 M HCl was added dropwise with swirling. HCl was added until the pH of the solution was distinctly acidic to pH paper. The solution was gently cooled and the side of the flask was gently scratched with a glass rod to induce recrystallization. The crude product was suction filtered using a Buchner or Hirsch funnel and was washed with three small portions of cold water. The crystals were allowed to air dry for several minutes while suction continued to eliminate excess water.The crude product was recrystallized from ethyl acetate. The dried crystals were weighed and a melting point was obtained. Results: Table 1: Experimental Data Table Initial Mass of Vanillin| 0. 3843 g| Final Mass of Vanillyl Alcohol| 0. 2467 g| Melting Point Range of Vanillyl Alcohol| 75-90Â °C| Percent Yield| 63. 99 % yield| Discussion: The purpose of this lab was to reduce vanillin to vanillyl alcohol. The mechanism of the lab involved reduction. Sodium borohydride was used to reduce the aldehyde on the vanillin molecule, which left the oxygen with a negative charge. Feature Article Relative Rates:Â  Free-Radical BrominationHCl then reacted with the negative oxygen on vanillin, and the oxygen then became protonated, which made another alcohol on the benzene ring. The melting point range obtained for vanillyl alcohol was between 75-90Â °C. The actual melting point was 115Â °C, which was approximately 25 degrees higher than the experimental values. The reason for this melting point difference can be attributed to impurities that developed throughout the procedure. The percent yield from the original sample was 63. 9%. A decent percentage of the original sample was lost throughout the reduction process of vanillin to vanillyl alcohol. Conclusion: Vanillin was reduced to vanillyl alcohol which obtained a melting point of 75-90Â °C. The percent yield from the original sample was 63. 99%. The mechanism involved the reduction of vanillin to vanillyl alcohol, which increased the number of bonds to hydrogen and decreased the number of bonds to oxygen by the reduction of a carbonyl.

Wednesday, January 8, 2020

Amphibious Warfare During The Continental Navy - 1687 Words

Amphibious Warfare in the Early Continental Navy The prospect of amphibious invasion has historical been one of the most logistically difficult to coordinate military operations. This can be clearly seen in the case of the Penobscot Expedition of 1779, which is recognized as the worst defeat of the U.S. preceding the Attack on Pearl Harbor. However, not thirty years later, combined American land and naval elements launched a success overland assault and coordinated naval bombardment on the fortress of Derne, protecting the city of Tripoli, forcing its capitulation on 27 April 1805. The difference between these two attacks stems not from major advancements in technology or ease of the assault on Derne, but from the underlying organization and coordination of the assaults. Preparations for the Penobscot Expedition began in response to the establishment of Fort George at Majabigwaduce, a small Loyalist town in modern-day Maine, under British General Francis McLean, commander of His Maje sty’s forces at Majabigwaduce (Greenburg 98). Being that Maine was a part of Massachusetts at the time, it was left to this state to remove the British forces before they could establish a proper base to deter American shipping and privateer raiding. To this end, the Massachusetts Council tasked Brigadier-General Solomon Lovell, â€Å"consult with the Commander of the fleet that the Naval Force may cooperate with the troops under your command in Endeavoring to Captivate Kill or Destroy the wholeShow MoreRelatedCompare and Contrast of the Army and the Marines Essay example1004 Words   |  5 Pagesforces of the United States. They consist of the Army, Navy, Marine Corps, Air Force, and the Coast Guard. 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